9th Class Chapter 2 Is Matter Around Us Pure or Not
Mixtures, Solubility & Separation Techniques
Exercises & Detailed Answers
1. Which Separation Technique?
For each mixture, choose the best physical method to separate the components:
- (a) Sodium chloride from its solution in water
- (b) Ammonium chloride from a mixture containing sodium chloride & ammonium chloride
- (c) Small metal pieces in car engine oil
- (d) Different pigments from flower-petal extract
- (e) Butter from curd
- (f) Oil from water
- (g) Tea leaves from tea
- (h) Iron pins from sand
- (i) Wheat grains from husk
- (j) Fine mud particles suspended in water
Answers:
- (a) Evaporation / Crystallization
- (b) Sublimation of ammonium chloride
- (c) Filtration (plus magnetic separation if needed)
- (d) Paper (or column) chromatography
- (e) Churning (centrifugation) to split butter (fat) from buttermilk
- (f) Separating funnel (density difference)
- (g) Filtration (tea strainer or filter paper)
- (h) Magnetic separation
- (i) Winnowing (air‐flow removes lighter husk)
- (j) Filtration or sedimentation + decantation
2. Steps to Make Tea
Describe the process using these terms: solution, solvent, solute, dissolve, soluble, insoluble, filtrate, residue.
- Boil water (the solvent) in a pan.
- Add tea leaves and let the soluble flavors dissolve, forming a tea solution.
- The insoluble leaves remain intact as the residue.
- Pour the mixture through a strainer (filter). The liquid collected is the filtrate – your tea.
- Optionally, add sugar (solute) and stir until it dissolves.
3. Solubility Data & Questions
Solubility (g solute per 100 g water) at various temperatures:
Substance | 283 K | 293 K | 313 K | 333 K | 353 K |
---|---|---|---|---|---|
Potassium nitrate (KNO₃) | 21 | 32 | 62 | 106 | 167 |
Sodium chloride (NaCl) | 36 | 36 | 37 | 38 | 39 |
Potassium chloride (KCl) | 34 | 35 | 40 | 46 | 54 |
Ammonium chloride (NH₄Cl) | 24 | 27 | 41 | 55 | 66 |
-
Mass of KNO₃ for 50 g water at 313 K?
Solubility = 62 g per 100 g water ⇒ for 50 g water ⇒ 62×0.5 = 31 g. -
Cooling KCl solution made at 353 K down to room T:
At 353 K it dissolves 54 g per 100 g water. At 293 K its solubility drops to 35 g. So 19 g of KCl will crystallize out as the solution cools. -
Solubility at 293 K & highest:
- KNO₃: 32 g
- NaCl: 36 g
- KCl: 35 g
- NH₄Cl: 27 g
⇒ NaCl has the highest solubility at 293 K. -
Effect of temperature on solubility:
In general, the solubility of most salts (endothermic dissolution) increases with temperature. Some (like NaCl) change only slightly.
4. Definitions & Examples
- Saturated solution: contains the maximum solute at a given T. e.g. a sugar–water solution that cannot dissolve more sugar at 25 °C.
- Pure substance: single chemical composition throughout. e.g. distilled water, crystalline sodium chloride.
- Colloid: intermediate particle size (1–100 nm), Tyndall effect visible. e.g. milk, fog, gelatin sol.
- Suspension: large particles that settle on standing. e.g. muddy water, chalk in water.
5. Homogeneous vs Heterogeneous Mixtures
- Soda water – homogeneous
- Soil – heterogeneous
- Vinegar – homogeneous
- Filtered tea – homogeneous
6. Confirming Pure Water
Tests you can perform:
- Measure boiling point ⇒ should be 100 °C at 1 atm
- Measure freezing point ⇒ 0 °C
- Check electrical conductivity ⇒ pure water conducts very poorly
- Sensory test (taste/smell) ⇒ should be neutral
7. Which are Pure Substances?
Identify which of the following qualify as pure substances:
- (a) Ice
- (b) Milk
- (c) Iron
- (d) Hydrochloric acid
- (e) Calcium oxide
- (f) Mercury
- (g) Brick
- (h) Wood
- (i) Air
Answers:
Pure substances: (a) Ice, (c) Iron, (d) Hydrochloric acid, (e) Calcium oxide, (f) Mercury
Pure substances: (a) Ice, (c) Iron, (d) Hydrochloric acid, (e) Calcium oxide, (f) Mercury
8. Identify the Solutions
Choose which of the following are solutions (homogeneous mixtures):
- (a) Soil
- (b) Sea water
- (c) Air
- (d) Coal
- (e) Soda water
Answers:
Solutions: (b) Sea water, (c) Air, (e) Soda water
Solutions: (b) Sea water, (c) Air, (e) Soda water
9. Tyndall Effect
Which of the following mixtures show the Tyndall effect?
- (a) Salt solution
- (b) Milk
- (c) Copper sulphate solution
- (d) Starch solution
Answers:
Tyndall effect visible in: (b) Milk, (d) Starch solution
Tyndall effect visible in: (b) Milk, (d) Starch solution
10. Classify the Samples
Label each of the following as an element, compound or mixture:
- (a) Sodium
- (b) Soil
- (c) Sugar solution
- (d) Silver
- (e) Calcium carbonate
- (f) Tin
- (g) Silicon
- (h) Coal
- (i) Air
- (j) Soap
- (k) Methane
- (l) Carbon dioxide
- (m) Blood
Answers:
- Elements: (a) Sodium, (d) Silver, (f) Tin, (g) Silicon
- Compounds: (e) Calcium carbonate, (k) Methane, (l) Carbon dioxide
- Mixtures: (b) Soil, (c) Sugar solution, (h) Coal, (i) Air, (j) Soap, (m) Blood
11. Chemical Changes
Identify which of the following are chemical changes:
- (a) Growth of a plant
- (b) Rusting of iron
- (c) Mixing of iron filings and sand
- (d) Cooking of food
- (e) Digestion of food
- (f) Freezing of water
- (g) Burning of a candle
Answers:
Chemical changes: (a) Growth of a plant, (b) Rusting of iron, (d) Cooking of food, (e) Digestion of food, (g) Burning of a candle
Chemical changes: (a) Growth of a plant, (b) Rusting of iron, (d) Cooking of food, (e) Digestion of food, (g) Burning of a candle
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